Diamond
A diamond is a hard mineral made of clean carbon. The diamond crystallized hundreds of millions of years ago into a crystalline crystal at a pressure of about 60,000 atmospheres at a temperature of about 1200 to 1600 degrees Celsius at a depth of about 200-250 kilometers below the earth's surface. The diamonds were made of two types of rocks: ecological rock and peridotite rock. With the movements of the tectonic plates and the harsh convection actions, the fluid of the trend is sometimes created to the surface, bearing diamond crystals inside. When the incursions burst into the surface, the erosion dissolved the penetration rock, which is soft relative to the diamond. The diamonds were washed, sank into streams and sometimes even reached the sea. These are the secondary mining sources. The penetration that did not reach the surface becomes an initial mining source, which is found in kimberlite or mphroite rocks.
The diamond crystal belongs to the cube system and appears in nature as a octagon or cube. The diamond is one of the alotropic of carbon. Another well known alotrop is graphite.
Most of the diamonds are invisible to the inexperienced and colorless. In their gemological grading they are included in the usual color group, even if they have a very low level of yellow and even light brown tones. Some levels of color intensity are included in the Fancy Color Diamonds.
For every 10,000 diamonds produced in the world, one colored diamond is found, which may be yellowish or brown, which is the most common. The more rare colors - green, blue, pink, orange, black, and the rarer - red, appear very low, up to one million.
The colored diamonds receive their special colors thanks to foreign atoms caught in them during the crystallization of the diamond in nature or by structural deformations in the diamond lattice: yellow, orange and brown are obtained by nitrogen atoms that penetrated the diamond during its crystallization, blue is obtained from the penetration of the boron, , The addition of graphite produces black diamonds, and structural deformations in the diamond lattice are responsible for the pink and red colors.
The prices of rough diamonds are determined by the various classification categories relating to shape, size, color and cleanliness. The price of polished diamonds is also determined by the quality of the polishing. The polished diamond rating is known as the four Cs - four words that begin with the English letter C and define the characteristics of the polished diamond as they appear in the gemological grading certificates - Carat, Color, Clarity, Cut - And finish level).
The division into the four Cs was developed in the late 1930s by the founder of the leading American gemological laboratory, Shifley.
The diamond is the hardest and most brilliant mineral: its level of difficulty is 10 Mohs Scale - the highest degree of difficulty in nature. The unique weight of the diamond 3.52. The coefficient of breaking its rays of light - 2.417 creates the glow and brilliance, which give the diamond its special beauty after its polishing.
The quality of most of the diamonds produced worldwide can not be processed as gem quality, either because of inclusions or severe structural problems. Over the years, industrial diamonds accounted for about 80% of the natural diamond production. In 1967, the diamond conglomerate De Beers, which was the exclusive channel for the supply of rough diamonds at the time, split the category of industrial diamonds, creating another category - Near Gem Quality. According to the new division: about 20% are defined as decorative diamonds, about 45% are defined as semi-decorative diamonds, and about 35% are defined as industrial diamonds. The motive for De Beers' move was the decline in the profitability of industrial diamonds following the advent of the synthetic diamond, which is preferable to the natural diamond industry. At the same time, the De Beers Corporation discovered India as the land of unlimited possibilities for making industrial rough a quality of almost ornamental because of cheap wages, which enabled the processing of large quantities of small diamonds at low quality.
Industrial diamonds are called Boart or Carbonado. Some of them are shredded and used as a diamond polishing powder (because of the hardness of a diamond, only a diamond can be polished), and some are routed to the industry: drilled heads for rock drilling, concrete, glass lens polishing, dental drills, Today, there are machines for artificially producing diamonds, although it is not possible to produce white diamonds. These diamonds are used mainly by IAI. In addition, there are diamond cutting and polishing machines that enable the cutting of rough diamonds in the most optimal way, while demonstrating the diamond's truth, so that the number of diamonds with the highest degree of cleanliness and the optimal and most profitable sizes will be produced.
Diamond structure
Like graphite, the diamond is made up of a single element, carbon, but the crystal forms of these two materials are very different. The phenomenon is called "polymorphism" and is the property of a permanent chemical compound that appears in several crystalline forms.
The diamond is an atomic lattice. The carbon atoms in the crystals are arranged so that each atom creates covalent bonds with four other atoms nearby, so that around each atom a structure of four carbon atoms is arranged in the vertices of a tetrahedron. This structure is extremely stable (low energy level), because the electron pairs involved in the perfect covalent bonds are as far apart as possible. The stability of the structure is what gives the diamond its strength and hardness.
Natural Diamonds
The diamond was created at depths of 200-250 kilometers at temperatures of about 1,000 to 1,200 degrees Celsius at a pressure of about 60,000 atmospheres.
These conditions exist beneath the Earth's crust under the most ancient continents, such as in South Africa, Siberia, Western Canada or Brazil. Apparently the diamonds are made from coal-rich compounds.
In a slow cooling process the carbon solidified and crystallized into the diamond, absorbing substances from its environment, which would determine its color, and would be one of the factors determining its level of cleanliness.
The diamonds made their way to the surface of the earth using rocks of various kinds, mainly kimberlite rocks (named after Kimberley, which was built near the first diamond mine built in South Africa in the 1870s), and Salafi Lamproit. The kimberlite, a relatively soft rock that rises faster than the rocks around it, bursts from a depth of 150-200 km in the form of a carrot, a dike or a sill, in order to locate the kimberlite rocks, usually covered with layers of soil and rock, About 10% of the world's kimberlite rocks contain diamonds, and less than 1% is considered an economic kimberlite (with a commercial diamond content of both quantity and monetary value).
Measurement
There is no uniform and absolute international standard for determining the quality of a diamond, and involves various tests, most of which are carried out by humans, and their outcome depends to a great extent on their expertise. This is one of the characteristics of the global diamond industry, which finds it very difficult to create a uniform standard for diamond valuation. Several gemological laboratories in the world are considered to be leading, documenting diamonds. The most prestigious and rigid laboratory in the world is the American Gemological Laboratory (GIA).
Clarity
The level of clarity of the diamond, which is referred to in commercial jargon as cleanliness, refers to the defects and the roughness of the diamond - inside and on the surface of the face. The clarity of the diamond's dives will be determined by the type of the inclusions or defects, their size, location, visibility, etc. This is the hierarchical ladder used by the American laboratory GIA:
FL (no inclusions and imperfections) - A diamond with no inclusions or internal or external defects visible to the eye of a gemologist is 10 times more magnified.
IF (no inclusions) - a diamond with no inclusions but only visible defects of a specialist gemologist at 10 times magnification.
VVS1 (very very small inclusions) tiny inclusions that even a specialist gemologist finds it difficult to see in 10 times magnification level 1.
VVS2 (very very small inclusions) - tiny inclusions that even a specialist gemologist finds it difficult to see in 10 times magnification level 2.
VS1 (very small inclusions) - very small inclusions, some of which will be difficult to distinguish even by a specialist gemologist at 10 times magnification level 1
VS2 (very small inclusions) - very small inclusions, some of which will be difficult to distinguish even by a specialist gemologist at 10 times magnification level 2.
SI1 (inclusions are visible) - small inclusions that a specialist gemologist can easily distinguish by 10 times magnification level 1.
SI2 (inclusions are visible) - small inclusions that a specialist gemologist can easily distinguish by 10 times magnification level 2.
I1 (many inclusions) - inclusions that are easily visible at magnification 10 times and sometimes without magnification. These defects may affect the sparkle and transparency of the diamond.
Level 1.
I2 (many inclusions) - inclusions that are easily visible at magnification 10 times and sometimes without magnification. These defects may affect the sparkle and transparency of the diamond. Level 2.
I3 (many inclusions) - inclusions that are easily visible at magnification 10 times and sometimes without magnification. These defects may affect the sparkle and transparency of the diamond. Level 3.
The color of the diamond
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It is customary to divide the diamonds into two main groups - regular colors and special colors (colored diamonds). Each group has its own rating scale.
The usual color group
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The usual color group includes diamonds from the clear, colorless, so-called white, to bright yellows and even light browns. The yellows are light in their various shades and are the most common in nature due to the conditions and processes that existed during the formation of diamonds. The usual color scale is marked with the letters D - Z (because at the time the ABC letters were used to mark diamonds in the commercial sector). The letter D marks a completely colorless diamond. The higher the letters, the more the color of the diamond is yellowish. The letter Z symbolizes very yellow diamonds that are not yet considered colored diamonds. For the most part, low-colored diamonds are not wanted and their prices are cheap.
It is important to note that the differences between the level of diamond color and the one after or before it are so minimal that even an expert in the field can find it difficult to identify the exact color without professional accessories such as lighting, color paper and so on. The fact is intensified in cases where the diamond is already embedded in the jewel. The yellowing of the diamond begins to be visible in H-I colors, and there too, it is very light yellowish, especially in cases where there is another white diamond for comparison.
Special color group
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This group includes the strong yellows and the special colors resulting from yellows, such as: blue, orange, green, pink, red, purple, dark brown and black. The special colors are created due to the penetration of foreign substances and chemical components into the diamond body when it is formed at a higher dose than the usual color diamonds, causing excessive absorption of certain colors and strong accentuation of other shades or structural deformations.
The colors of colored diamonds, or their commercial name Fancy color diamonds, are measured in a completely different way, with the most important criterion being the color intensity of the diamond. Determination of the color of the diamond takes into account three main parameters - tint (there are 27 different shades), brightness or dark color and depth of color.
The color of the diamond: There is a table of 27 different shades to classify the diamond. In cases where the diamond has two distinct shades, it determines the dominant shade and marks it first in the gemological certificate.
Brightness / Darkness Alongside the color depth of the diamond
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each colored diamond will be graded according to its brightness or darkness ranging from very bright to very dark. After determining the degree of brightness or darkness of the diamond color, the gemologist who evaluates the diamond will determine its color depth and the grade will range from weak to strong. After the gemologist has determined these two parameters, he will cross between them in a graph of two parameters (darkness and depth). The cross between the color depth of the diamond and its brightness / darkness will determine the color intensity on the next hierarchical ranking scale (the first is the least qualitative and the last is the most High quality):
Fancy Light
Fancy
Fancy Intense
Fancy Dark
Fancy Deep
Fancy Vivid
Another variable that influences diamond color determination is the color distribution of the diamond and its color uniformity.
The inner color of the colored diamond will not necessarily be exposed without proper polishing. There are diamond polishers specializing in colored diamonds and all their work is to expose the inner color of the diamond by its correct polishing.
Fluorescent diamond
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Another index that affects the price of a diamond and its perceived quality is the diamond's fluorescent index. Many diamonds emit bluish light when placed under a UV bulb (which distributes ultraviolet rays). For colorless diamonds, high fluorescence is considered to create a viscosity in their appearance and therefore reduces them. For yellowish diamonds, high fluorescence is a positive thing because it whitens them. There are quite a few reviews about the use of the fluorescent index in diamond pricing and there are quite a few claims that the fluorescence in the diamond does not affect its appearance. Either way, it is the criterion that affects the price of the diamond, especially in the higher weight ranges, so be aware of it.
Diamond polishing
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The hustle is the desktop of the plank. The mulch is composed of the way the diamond sets the side to which the rough diamond is glued. The polishing work takes several hours or even days - depending on the size of the rough to polish. The polishing work is ancient and the method of polishing has not changed from the previous century. At the same time, the polishing technology has progressed immeasurably over the past 30 years.
Today, before the start of the polishing work, computer software is used to read the rough and show the ideal model for polishing the diamond. In addition, there are today used automatic polishing machines for small white diamonds.
In the Fancy Color field, the work of the diamond is still significant and unique. Therefore, despite the supporting technologies, the work of the polishing is important and decisive.
In the past, the State of Israel was one of the most important diamond polishing centers in the world. But since the 1980s, it has lost its status when most manufacturing has moved to East Asia, mainly to India and China, where wages are significantly lower.
White diamond polishing
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The quality of diamond polishing has a direct impact on its appearance and price. A rough diamond is lifeless and does not sparkle and only its correct polishing achieves its ability to return light. In recent decades, all the round diamonds have been polished in the form of modern polishing with very clear rules for the number of diamond wigs and their proportion, a proper proportion between the diameter of the diamond and its height. The reason for the change was a technological advance that allowed for a deeper understanding of the best way to make light rays stay longer inside the diamond and thus increase the light it produces. The modern standards for diamond polishing are based largely on the development of Marcel Tolkowsky at the beginning of the 20th century.
As with the other diamond characteristics, there is no uniform international standard for diamond polishing, but relatively speaking it is the most scientific criterion in its nature and the differences between the various modern cutting standards are relatively small. In the gemstone certificate of the Zion diamond, the cut consists of three different parameters - polishing, polishing and symmetry.
Polishing of colored diamonds
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In contrast to white diamonds where the goal of polishing is to maximize the diamond's ability to return the light, the goal of polishing colored diamonds is to maximize the color of the diamond and give it extra power. The specialty in polishing colored diamonds is special expertise and requires very high skill. In contrast to a round cut of white diamonds that maximizes the potential of the diamond, in colored diamonds, diamonds are hardly polished because this is not a form that maximizes the color of the diamond. For this reason it is customary to polish the diamond into different shapes such as drop, radiant, heart, emerald, marquise and more mainly according to current fashion and taste of the crowd. A very important consideration in determining the shape of the polished diamond is to maintain the maximum weight of the diamond after it is polished. The final consideration is, as stated, the extraction of the diamond's color ability and strength.
The diamond industry can be separated into two distinct categories: one dealing with gem-grade diamonds and another for industrial-grade diamonds. Both markets value diamonds differently.
Only a very small fraction of the diamond ore consists of actual diamonds. The ore is crushed, during which care is required not to destroy larger diamonds, and then sorted by density. Today, diamonds are located in the diamond-rich density fraction with the help of X-ray fluorescence, after which the final sorting steps are done by hand. Before the use of X-rays became commonplace, the separation was done with grease belts; diamonds have a stronger tendency to stick to grease than the other minerals in the ore.
Historically, diamonds were found only in alluvial deposits in Guntur and Krishna district of the Krishna River delta in Southern India. India led the world in diamond production from the time of their discovery in approximately the 9th century BC to the mid-18th century AD, but the commercial potential of these sources had been exhausted by the late 18th century and at that time India was eclipsed by Brazil where the first non-Indian diamonds were found in 1725. Currently, one of the most prominent Indian mines is located at Panna.
Diamond extraction from primary deposits (kimberlites and lamproites) started in the 1870s after the discovery of the Diamond Fields in South Africa. Production has increased over time and now an accumulated total of 4,500,000,000 carats (900,000 kg) have been mined since that date. Twenty percent of that amount has been mined in the last five years, and during the last 10 years, nine new mines have started production; four more are waiting to be opened soon. Most of these mines are located in Canada, Zimbabwe, Angola, and one in Russia.
In the U.S., diamonds have been found in Arkansas, Colorado, New Mexico, Wyoming, and Montana. In 2004, the discovery of a microscopic diamond in the U.S. led to the January 2008 bulk-sampling of kimberlite pipes in a remote part of Montana. The Crater of Diamonds State Park in Arkansas is open to the public, and is the only mine in the world where members of the public can dig for diamonds.
Today, most commercially viable diamond deposits are in Russia (mostly in Sakha Republic, for example Mir pipe and Udachnaya pipe), Botswana, Australia (Northern and Western Australia) and the Democratic Republic of the Congo. In 2005, Russia produced almost one-fifth of the global diamond output, according to the British Geological Survey. Australia boasts the richest diamantiferous pipe, with production from the Argyle diamond mine reaching peak levels of 42 metric tons per year in the 1990s. There are also commercial deposits being actively mined in the Northwest Territories of Canada and Brazil. Diamond prospectors continue to search the globe for diamond-bearing kimberlite and lamproite pipes.
Synthetic diamonds are diamonds manufactured in a laboratory, as opposed to diamonds mined from the Earth. The gemological and industrial uses of diamond have created a large demand for rough stones. This demand has been satisfied in large part by synthetic diamonds, which have been manufactured by various processes for more than half a century. However, in recent years it has become possible to produce gem-quality synthetic diamonds of significant size. It is possible to make colorless synthetic gemstones that, on a molecular level, are identical to natural stones and so visually similar that only a gemologist with special equipment can tell the difference.
The majority of commercially available synthetic diamonds are yellow and are produced by so-called high-pressure high-temperature (HPHT) processes. The yellow color is caused by nitrogen impurities. Other colors may also be reproduced such as blue, green or pink, which are a result of the addition of boron or from irradiation after synthesis.
Another popular method of growing synthetic diamond is chemical vapor deposition (CVD). The growth occurs under low pressure (below atmospheric pressure). It involves feeding a mixture of gases (typically 1 to 99 methane to hydrogen) into a chamber and splitting them to chemically active radicals in a plasma ignited by microwaves, hot filament, arc discharge, welding torch or laser. This method is mostly used for coatings, but can also produce single crystals several millimeters in size (see picture).
As of 2010, nearly all 5,000 million carats (1,000 tonnes) of synthetic diamonds produced per year are for industrial use. Around 50% of the 133 million carats of natural diamonds mined per year end up in industrial use. Mining companies' expenses average $40 to $60 per carat for natural colorless diamonds, while synthetic manufacturers' expenses average $2,500 per carat for synthetic, gem-quality colorless diamonds.[99]:79 However, a purchaser is more likely to encounter a synthetic when looking for a fancy-colored diamond because nearly all synthetic diamonds are fancy-colored, while only 0.01% of natural diamonds are.
A diamond simulant is a non-diamond material that is used to simulate the appearance of a diamond, and may be referred to as diamante.�Cubic zirconia�is the most common. The gemstone�moissanite�(silicon carbide) can be treated as a diamond simulant, though more costly to produce than cubic zirconia. Both are produced synthetically
Diamond enhancements are specific treatments performed on natural or synthetic diamonds (usually those already cut and polished into a gem), which are designed to better the gemological characteristics of the stone in one or more ways. These include laser drilling to remove inclusions, application of sealants to fill cracks, treatments to improve a white diamond's color grade, and treatments to give fancy color to a white diamond.
Coatings are increasingly used to give a diamond simulant such as cubic zirconia a more "diamond-like" appearance. One such substance is diamond-like carbon�an amorphous carbonaceous material that has some physical properties similar to those of the diamond. Advertising suggests that such a coating would transfer some of these diamond-like properties to the coated stone, hence enhancing the diamond simulant. Techniques such as Raman spectroscopy should easily identify such a treatment.
Early diamond identification tests included a scratch test relying on the superior hardness of diamond. This test is destructive, as a diamond can scratch another diamond, and is rarely used nowadays. Instead, diamond identification relies on its superior thermal conductivity. Electronic thermal probes are widely used in the gemological centers to separate diamonds from their imitations. These probes consist of a pair of battery-powered thermistors mounted in a fine copper tip. One thermistor functions as a heating device while the other measures the temperature of the copper tip: if the stone being tested is a diamond, it will conduct the tip's thermal energy rapidly enough to produce a measurable temperature drop. This test takes about 2�3 seconds.
Whereas the thermal probe can separate diamonds from most of their simulants, distinguishing between various types of diamond, for example synthetic or natural, irradiated or non-irradiated, etc., requires more advanced, optical techniques. Those techniques are also used for some diamonds simulants, such as silicon carbide, which pass the thermal conductivity test. Optical techniques can distinguish between natural diamonds and synthetic diamonds. They can also identify the vast majority of treated natural diamonds. "Perfect" crystals (at the atomic lattice level) have never been found, so both natural and synthetic diamonds always possess characteristic imperfections, arising from the circumstances of their crystal growth, that allow them to be distinguished from each other.
Several methods for identifying synthetic diamonds can be performed, depending on the method of production and the color of the diamond. CVD diamonds can usually be identified by an orange fluorescence.Similarly, natural diamonds usually have minor imperfections and flaws, such as inclusions of foreign material, that are not seen in synthetic diamonds.
Screening devices based on diamond type detection can be used to make a distinction between diamonds that are certainly natural and diamonds that are potentially synthetic. Those potentially synthetic diamonds require more investigation in a specialized lab. Examples of commercial screening devices are Diatrue (OGI Systems ).
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